Angelina Jolie dons brown pencil skirt at UN headquarters

Following the Toronto Film Festival premiere of her fifth directorial effort, Angelina Jolie met with United Nations Secretary General António Guterres at the Manhattan headquarters on Thursday.

The Special Envoy for the UN High Commissioner for Refugees easily defied her 41 years in a white silk blouse, brown pencil skirt, and nude pumps selected by stylist Jen Rade.

Hairstylist Adam Campbell blew out the Oscar winner’s naturally brunette locks and she finished off her business attire with diamond earring and a crimson pout and manicure.

  

Mysterious meeting: Following the TIFF premiere of her fifth directorial effort, Angelina Jolie met with UN Secretary General António Guterres at the Manhattan headquarters on Thursday

Rather than taking vacuous selfies or developing clothing lines, Angelina has made over 60 trips to the field as part of her work with the do-gooding intergovernmental organization.

On Wednesday, Jolie gave an update on her tough divorce from estranged third husband Brad Pitt after 12 years together.  

‘None of it’s easy. It’s very, very difficult, a very painful situation, and I just want my family healthy,’ the By the Sea director admitted to the New York Times.

‘They’re getting better.’  

Do-gooder: The Special Envoy for the UN High Commissioner for Refugees easily defied her 41 years in a white silk blouse, brown pencil skirt, and nude pumps selected by stylist Jen Rade

Do-gooder: The Special Envoy for the UN High Commissioner for Refugees easily defied her 41 years in a white silk blouse, brown pencil skirt, and nude pumps selected by stylist Jen Rade

Do-gooder: The Special Envoy for the UN High Commissioner for Refugees easily defied her 41 years in a white silk blouse, brown pencil skirt, and nude pumps selected by stylist Jen Rade

Flawless: Hairstylist Adam Campbell blew out the Oscar winner's naturally brunette locks and she finished off her business attire with diamond earring and a crimson pout and manicure

Flawless: Hairstylist Adam Campbell blew out the Oscar winner’s naturally brunette locks and she finished off her business attire with diamond earring and a crimson pout and manicure

Impressive: Rather than taking selfies or developing clothing lines, Angelina has made over 60 trips to the field as part of her work with the do-gooding intergovernmental organization

Impressive: Rather than taking selfies or developing clothing lines, Angelina has made over 60 trips to the field as part of her work with the do-gooding intergovernmental organization

Newly single: On Wednesday, Jolie gave an update on her tough divorce from estranged third husband Brad Pitt after 12 years together

Newly single: On Wednesday, Jolie gave an update on her tough divorce from estranged third husband Brad Pitt after 12 years together

The By the Sea director admitted to the New York Times: 'None of it's easy. It's very, very difficult, a very painful situation, and I just want my family healthy'

The By the Sea director admitted to the New York Times: ‘None of it’s easy. It’s very, very difficult, a very painful situation, and I just want my family healthy’

The former Hollywood wild child’s big blended brood – including Zahara, 12; Shiloh, 11; and twins Vivienne & Knox, 9 – attended the TIFF premiere of First They Killed My Father on Monday.

It currently holds a 76 percent critic approval rating on Rotten Tomatoes, a 70 percent approval rating on MetaCritic, and a 6.7/10 on IMDb.

The Khmer-language drama – which begins streaming Friday on Netflix – is based on human rights activist Loung Ung’s 2006 memoir about the 2M lives lost during the Cambodian genocide 40 years ago.

Angelina’s 16-year-old son Maddox (born Rath Vibol) received an executive-producing credit for the film and her 13-year-old son Pax shot still photography for it. 

'They're getting better': The former Hollywood wild child's big blended brood - including Zahara, 12; Shiloh, 11; and twins Vivienne & Knox, 9 - attended the TIFF premiere of First They Killed My Father on Monday

‘They’re getting better’: The former Hollywood wild child’s big blended brood – including Zahara, 12; Shiloh, 11; and twins Vivienne & Knox, 9 – attended the TIFF premiere of First They Killed My Father on Monday

Begins streaming Friday on Netflix! The Khmer-language drama is based on human rights activist Loung Ung's 2006 memoir about the 2M lives lost during the Cambodian genocide 40 years ago

Begins streaming Friday on Netflix! The Khmer-language drama is based on human rights activist Loung Ung’s 2006 memoir about the 2M lives lost during the Cambodian genocide 40 years ago

'We're really such a unit': Angelina's 16-year-old son Maddox (L) received an executive-producing credit for the film and her 13-year-old son Pax (M) shot still photography for it

‘We’re really such a unit’: Angelina’s 16-year-old son Maddox (L) received an executive-producing credit for the film and her 13-year-old son Pax (M) shot still photography for it

‘They really help me so much. We’re really such a unit,’ Jolie gushed.

‘They’re the best friends I’ve ever had. Nobody in my life has ever stood by me more.’

Earlier this month, the Kung Fu Panda 3 actress confirmed she would soon begin production on the sequel to the hit Disney villain origin story Maleficent.

‘I am now the breadwinner for the family so it’s time,’ Angie told Deadline on September 3. 

'I am now the breadwinner for the family': Earlier this month, the Kung Fu Panda 3 actress confirmed she would soon begin production on the sequel to Disney's Maleficent

‘I am now the breadwinner for the family’: Earlier this month, the Kung Fu Panda 3 actress confirmed she would soon begin production on the sequel to Disney’s Maleficent

Based on Deborah Ellis' 2001 novel: But first, Jolie executive-produced the Afghanistan-set animated feature The Breadwinner, which hits US theaters November 17 and UK theaters May 25

Based on Deborah Ellis’ 2001 novel: But first, Jolie executive-produced the Afghanistan-set animated feature The Breadwinner, which hits US theaters November 17 and UK theaters May 25

‘We have been working on the script and this is going to be a really strong sequel.’

But first, Jolie executive-produced the Afghanistan-set animated feature The Breadwinner, which hits US theaters November 17 and UK theaters May 25.

Nora Twomey’s flick, based on the 2001 novel by Deborah Ellis, centers on a headstrong girl who disguises herself as a boy to provide for her family after her father gets arrested.

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